Log pre-master keys during TLS v1.3 handshake

Is there a way to save the pre-master keys which are encrypted TLS
handshake between PostgreSQL server and psql client due to a TLS handshake?
For example, in a Chrome you can save those keys due to connecting through
HTTPS with option --ssl-key-log-file or an environment variable
SSLKEYLOGFILE (
https://knowledgebase.paloaltonetworks.com/KCSArticleDetail?id=kA14u000000wkvECAQ&lang=en_US%E2%80%A9
).
I need the similar feature, at least in psql client (ideally, on the
postgresql server side too).

Why I need this:
I'm debugging TLS connection to postgres from a rust application, used
postgres-native-tls
library. A psql client makes a successful TLS v1.3 connection, but my based
on postgres-native-tls client fails with an "error performing TLS
handshake" message. I want to dump tcp trafic, and analyze it in the
Wireshark, what exactly certificates exchanged between the psql and
Postgresql (succeeded TLS session), then between postgres-native-tls and
postgres, and then to compare them. Buuut... to view the certificates in
Wireshark, you need the TLS pre-master keys to decrypt the Encrypted
Extensions packets.