problem with the Index

I have a problem with the index of 1 table.

I hava a table created :
CREATE TABLE "acucliart" (
"cod_pto" numeric(8,0) NOT NULL,
"cod_cli" varchar(9) NOT NULL,
"mes" numeric(2,0) NOT NULL,
"ano" numeric(4,0) NOT NULL,
"int_art" numeric(5,0) NOT NULL,
"cantidad" numeric(12,2),
"ven_siv_to" numeric(14,2),
"ven_civ_to" numeric(14,2),
"tic_siv_to" numeric(14,2),
"tic_civ_to" numeric(14,2),
"visitas" numeric(2,0),
"ult_vis" date,
"ven_cos" numeric(12,2),
"ven_ofe" numeric(12,2),
"cos_ofe" numeric(12,2),
CONSTRAINT "acucliart_pkey"
PRIMARY KEY ("cod_cli")
);

if i do this select:
explain select * from acucliart where cod_cli=10000;
postgres use the index
NOTICE: QUERY PLAN:
Index Scan using cod_cli_ukey on acucliart (cost=0.00..4.82 rows=1
width=478)

and this select
explain select * from acucliart where cod_cli>10000;
Postgres don't use the index:
NOTICE: QUERY PLAN:
Seq Scan on acucliart (cost=0.00..22.50 rows=333 width=478)

why?

tk